Synthesis of µ<sub>3</sub>-alklidynetrimetal complexes: X-ray crystal structures of [FePtW(µ<sub>3</sub>-CC<sub>6</sub>H<sub>4</sub>Me-4)(CO)<sub>6</sub>(PEt<sub>3</sub>)(η-C<sub>5</sub>H<sub>5</sub>)] and [FeRhW(µ<sub>3</sub>-CC<sub>6</sub>H<sub>4</sub>Me-4)(µ<sub>2</sub>-CO)(CO)<sub>5</sub>(η-C<sub>5</sub>H<sub>5</sub>)(η-C<sub>9</sub>H<sub>7</sub>)] - Concepedia

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Synthesis of µ<sub>3</sub>-alklidynetrimetal complexes: X-ray crystal structures of [FePtW(µ<sub>3</sub>-CC<sub>6</sub>H<sub>4</sub>Me-4)(CO)<sub>6</sub>(PEt<sub>3</sub>)(η-C<sub>5</sub>H<sub>5</sub>)] and [FeRhW(µ<sub>3</sub>-CC<sub>6</sub>H<sub>4</sub>Me-4)(µ<sub>2</sub>-CO)(CO)<sub>5</sub>(η-C<sub>5</sub>H<sub>5</sub>)(η-C<sub>9</sub>H<sub>7</sub>)]

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Citations

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References

1980

Year

Michael J. Chetcuti, Michael Green, Judith A. K. Howard, John C. Jeffery, Rona M. Mills, Geoffrey N. Pain, Simon J. Porter, F. G. A. Stone, Audrey A. Wilson, Peter Woodward

Journal of the Chemical Society Chemical Communications

Materials ScienceInorganic ChemistryTriangular ArrangementsCluster ComplexesEngineeringAlkylidyne LigandsCoordination ComplexCluster ChemistryOrganometallic CatalysisCatalysisMolecular ComplexChemistryX-ray Crystal StructuresInorganic SynthesisInorganic Compound

Abstract

Methods for synthesis of cluster complexes containing triangular arrangements of metal atoms capped by alkylidyne ligands are reported, and such structures confirmed by X-ray diffraction studies on the compounds [FePtW(µ3-CC6H4Me-4)(CO)6(PEt3)(η-C5H5)] and [FeRhW(µ3-CC6H4Me-4)(µ2-CO)(CO)5(η-C5H5)(η-C9H7)].