First structural characterisation of penta- and hexa-phosphorus analogues of ferrocene. Synthesis, crystal and molecular structure of the air-stable, sublimable iron sandwich compounds [Fe(η<sup>5</sup>-C<sub>2</sub>R<sub>2</sub>P<sub>3</sub>)<sub>2</sub>], and [Fe(η<sup>5</sup>-C<sub>3</sub>R<sub>3</sub>P<sub>2</sub>)(η<sup>5</sup>-C<sub>2</sub>R<sub>2</sub>P<sub>3</sub>)](R = Bu<sup>t</sup>) - Concepedia

Concepedia

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First structural characterisation of penta- and hexa-phosphorus analogues of ferrocene. Synthesis, crystal and molecular structure of the air-stable, sublimable iron sandwich compounds [Fe(η<sup>5</sup>-C<sub>2</sub>R<sub>2</sub>P<sub>3</sub>)<sub>2</sub>], and [Fe(η<sup>5</sup>-C<sub>3</sub>R<sub>3</sub>P<sub>2</sub>)(η<sup>5</sup>-C<sub>2</sub>R<sub>2</sub>P<sub>3</sub>)](R = Bu<sup>t</sup>)

82

Citations

0

References

1987

Year

Rainer Bartsch, Peter B. Hitchcock, John F. Nixon

Journal of the Chemical Society Chemical Communications

Materials ScienceInorganic ChemistryInorganic CompoundEngineeringBiochemistrySublimable Iron SandwichNatural SciencesCoordination ComplexHexa-phosphorus AnaloguesFunctional MaterialsChemistryInorganic MaterialCrystallographyInorganic SynthesisStructural Characterisation

Abstract

The first structurally characterised penta- and hexa-phosphorus analogues of ferrocene, bis-(η5–2,5-di-t-butyl-1,3,4-triphosphacyclopentadienyl)iron and (η5-2,4,5-tri-t-butyl-1,3-diphosphacyclopentadienyl)-(η5-2,5-di-t-butyl-1,3,4-triphosphacyclopentadienyl)iron, are described.