Concepedia

Palladium-Catalyzed [4 + 3] Intramolecular Cycloaddition of Alkylidenecyclopropanes and Dienes

Moisés Gulı́as, Juan Durán, Fernando López, Luis Castedo, José L. Mascareñas

Journal of the American Chemical Society · 2007 · 124 citations · 6 references

DOI

Concepts

Abstract

Octa-5,7-dienylidenecyclopropanes undergo [4 + 3] intramolecular cycloaddition reactions upon treatment with appropriate palladium catalysts to give stereochemically rich bicyclo[5.3.0]octane systems in a completely diastereoselective manner.

References

6

Studies in natural products chemistry

John Mann · Phytochemistry · 1998 · 406 citations

, , +12

Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes:  A Rapid, Practical Approach to Bicyclo[3.3.0]octenes

Alejandro Delgado, Ramón Rodríguez, Luis Castedo et al. · Journal of the American Chemical Society · 2003 · 106 citations

, , +9

Transition metal templates as guides for cycloadditions

Barry M. Trost · Pure and Applied Chemistry · 1988 · 85 citations · Full text

, , +7

CHO vs. CH:CH2 competition in radical cyclizations: is the 5-hexenyl radical really supreme?

R. TSANG, John K. Dickson, Helen Pak et al. · Journal of the American Chemical Society · 1987 · 82 citations

, , +10

Palladium-Catalyzed [3 + 2] Intramolecular Cycloaddition of Alk-5-enylidenecyclopropanes

Moisés Gulı́as, Rebeca García‐Fandiño, Alejandro Delgado et al. · Journal of the American Chemical Society · 2005 · 75 citations

, , +10