Concepedia

Synthesis and characterisation of a mixed-valence Mn<sub>13</sub>complex with S<sub>6</sub>symmetry by using 2-phenoxybenzoate

Alan Ferguson, Katrina Thomson, Andrew Parkin, Paul Cooper, Constantinos J. Milios, Euan K. Brechin, Mark Murrie

Dalton Transactions · 2006 · 20 citations · 14 references

DOI

Concepts

Abstract

The synthesis, structure and magnetic properties of [Mn(13)O(8)(OEt)6(O(2)CC(6)H(4)OPh)12] are reported as the first example of a high nuclearity manganese complex with 2-phenoxybenzoate: the complex possesses S6 symmetry and an S = 11/2 ground state.

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