Stable Intramolecularly Base-Stabilized Germylene− and Stannylene−Borane Adducts: M[C<sub>6</sub>H<sub>3</sub>(NMe<sub>2</sub>)<sub>2</sub>-2,6]<sub>2</sub>BH<sub>3</sub> (M = Ge, Sn) - Concepedia

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Stable Intramolecularly Base-Stabilized Germylene− and Stannylene−Borane Adducts: M[C<sub>6</sub>H<sub>3</sub>(NMe<sub>2</sub>)<sub>2</sub>-2,6]<sub>2</sub>BH<sub>3</sub> (M = Ge, Sn)

56

Citations

16

References

1998

Year

C. Drost, Peter B. Hitchcock, Michael F. Läppert

Organometallics

Inorganic ChemistryChemical EngineeringFour-coordinated GermaniumEngineeringMonomeric GermyleneAdducts Mar2Organometallic CatalysisMain Group ChemistryChemistryOrganometallic PolymerInorganic SynthesisBiomolecular EngineeringStannylene−borane Adducts

Abstract

The synthesis and characterization of two novel and thermally surprisingly stable main-group-element Lewis acid (BH3) adducts (3 and 4) of a monomeric germylene (1) and of a diarylstannylene (2) is reported. X-ray crystal structures of the adducts MAr2(BH3) reveal a four-coordinated germanium (3) but five-coordinated tin (4), with regard to the C,N-potentially bidentate chelating ligand -C6H3(NMe2)2-1,2 and BH3, respectively.

References

	Year	Citations

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