Journal of Fluid Mechanics · 1987 · 109 citations · 13 references
EngineeringChemical EngineeringChemistryFluid DynamicsFluid MechanicsRheologyFlow BehaviorPolymer AdditivesPolymer PhysicsPolymer RheologyRheological ModelingSuspension RheologyChannel FlowPolymer Rheology SimulationPolymer Solution Flow BehaviorPolymer Solution RheologyPolymer Solution ViscosityPolymeric Fluid DynamicsRheology Of Polymer SolutionsShear Properties Of Polymers
The conical-channel flow of a dilute polymer solution is investigated theoretically. The stress field due to polymer additive is calculated using a new molecular model, based on the physical picture of the polymer molecules unravelling in strong flows and Batchelor's theory for the stress in a suspension of elongated particles. Good agreement is obtained with the experimental results of James & Saringer (1980). The absence of a significant polymer effect in a two-dimensional case (the wedge-channel flow), observed by the same authors (James & Saringer 1982 a ), is also explained. The fundamental differences between the proposed model and the elastic-dumbbell models are discussed.
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Statistical mechanics of chain molecules
Paul J. Flory, M.V. Volkenstein · Biopolymers · 1969 · 6.5K citations
Natural Sciences, Chemistry, Physics +14
Dynamical Scaling for Polymers in Theta Solvents
F. Brochard, P. G. de Gennes · Macromolecules · 1977 · 374 citations
Mechanical models of dilute polymer solutions in strong flows
E. J. Hinch · The Physics of Fluids · 1977 · 334 citations