Concepedia

In situ Crystallization of Low-Melting Ionic Liquids

Angshuman Roy Choudhury, Neil Winterton, Alexander Steiner, Andrew I. Cooper, Kathleen A. Johnson

Journal of the American Chemical Society · 2005 · 260 citations · 17 references

DOI

Concepts

Abstract

Single crystals of five very low-melting ionic liquids, [emim]BF4 (mp -1.3 degrees C), [bmim]PF6 (+1.9 degrees C), [bmim]OTf (+6.7 degrees C), [hexpy]NTf2 (-3.6 degrees C), and [bmpyr]NTf2 (-10.8 degrees C), have been grown using a combined calorimetric and zone-melting approach and their crystal structures determined by X-ray diffraction.

References

17

Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts

Pierre Bonhôte, Ana-Paula Dias, N. Papageorgiou et al. · Inorganic Chemistry · 1996 · 4.3K citations · Full text

, , +17

Raman and Infrared Spectra and ab Initio Calculations of C<sub>2</sub><sub>-</sub><sub>4</sub>MIM Imidazolium Hexafluorophosphate Ionic Liquids

Erach R. Talaty, Sidhartha Raja, Vincent J. Storhaug et al. · The Journal of Physical Chemistry B · 2004 · 441 citations

, , +17

Small-Angle X-ray Scattering Studies of Liquid Crystalline 1-Alkyl-3-methylimidazolium Salts

A.E. Bradley, Christopher Hardacre, John D. Holbrey et al. · Chemistry of Materials · 2002 · 414 citations

, , +17

C-H-π Interactions in 1-n-Butyl-3-methylimidazolium Tetraphenylborate Molten Salt: Solid and Solution Structures

Jaı̈rton Dupont, Paulo A. Z. Suarez, Roberto F. De Souza et al. · Chemistry - A European Journal · 2000 · 255 citations · Full text

, , +16

Molecular Structure, Vibrational Spectra, and Hydrogen Bonding of the Ionic Liquid 1‐Ethyl‐3‐methyl‐1<i>H</i>‐imidazolium Tetrafluoroborate

Sergey A. Katsyuba, Paul J. Dyson, Elena E. Zvereva et al. · Helvetica Chimica Acta · 2004 · 207 citations · Full text

, , +17