Enantioselective route to a key intermediate in the total synthesis of forskolin

Nuclear magnetic resonance enantiomer regents. Configurational correlations via nuclear magnetic resonance chemical shifts of diastereomeric mandelate, O-methylmandelate, and .alpha.-methoxy-.alpha.-trifluoromethylphenylacetate (MTPA) esters

James A. Dale, Harry S. Mosher · Journal of the American Chemical Society · 1973 · 2.6K citations

Chemical Analysis, Magnetic Resonance, Altmetric Attention Score +16

Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications

E. J. Corey, Raman K. Bakshi, Saizo Shibata · Journal of the American Chemical Society · 1987 · 1.4K citations

Chemical Engineering, Engineering, Synthetic Implications +13

A stable and easily prepared catalyst for the enantioselective reduction of ketones. Applications to multistep syntheses

E. J. Corey, Raman K. Bakshi, Saizo Shibata et al. · Journal of the American Chemical Society · 1987 · 863 citations

Chemical Engineering, Enantioselective Reduction, Engineering +11

An efficient and catalytically enantioselective route to (S)-(-)-phenyloxirane

E. J. Corey, Saizo Shibata, Raman K. Bakshi · The Journal of Organic Chemistry · 1988 · 393 citations

Chemical Engineering, Enantioselective Route, Engineering +10

Total synthesis of (.+-.)-forskolin

E. J. Corey, Paul Da Silva Jardine, John C. Rohloff · Journal of the American Chemical Society · 1988 · 145 citations

Altmetrics, Biosynthesis, Bioorganic Chemistry +15