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Facile formation of exo-nido→closo-rearrangement products upon the replacement of PPh3 ligands with bis(diphenylphosphino)alkanes in “three-bridge” ruthenacarborane 5,6,10-[RuCl(PPh3)2]-5,6,10-(µ-H)3-10-H-exo-nido-7,8-C2B9H8

Inorganic ChemistryCross-coupling ReactionFacile FormationEngineeringOrganometallic CatalysisExo-nido→closo-rearrangement ProductsChemistryBiomolecular Engineering