Pd−Promoted Ni−P Electroless Deposition on a Hydrogen-Bonded Molecular Surface of a Supramolecular Fibrous Template

Abstract

A nickel−phosphorus (Ni−P) hollow microfiber was obtained by simply immersing a recyclable hydrogen-bonded supramolecular fibrous template made of amphoteric azopyridine carboxylic acid in an HCl-acidic PdCl2 aqueous solution and in a Ni−P electroless plating bath, followed by template removal in an alkaline aqueous solution. The Ni−P hollow microfiber had an inner pore diameter of 0.5 μm and a wall thickness of about 50 nm. The mechanism of the Pd-promoted Ni−P electroless deposition on the template surface was revealed by XPS analysis and TEM observation. Coordination of the [PdCl4]2- species and its subsequent hydrolysis and condensation polymerization to a tubular Pd2+ nanosheet and formation of the Pd0 nanoparticle as plating catalyst were brought about on the molecular surface of successive head-to-tail COOH···NC5H4 hydrogen bonds, which comprised the supramolecular fibrous template. The hydrogen-bonded surface ordered at a molecular level leading to the tubular Pd2+ nanosheet played an important role in homogeneous Pd-promoted Ni−P electroless deposition and allowed us to fabricate a uniform Ni−P hollow microfiber.