An expeditious and high-yield formal synthesis of hirsutene using Rh(I)-catalyzed [(5+2)+1] cycloaddition

A Computationally Designed Rh(I)-Catalyzed Two-Component [5+2+1] Cycloaddition of Ene-vinylcyclopropanes and CO for the Synthesis of Cyclooctenones

Yuanyuan Wang, Jingxin Wang, Jiachun Su et al. · Journal of the American Chemical Society · 2007 · 214 citations

Natural Sciences, Chemistry, Computational Design +16

Intramolecular Organocatalytic [3+2] Dipolar Cycloaddition: Stereospecific Cycloaddition and the Total Synthesis of (±)‐Hirsutene

Jian‐Cheng Wang, Michael J. Krische · Angewandte Chemie International Edition · 2003 · 180 citations · Full text

Natural Sciences, Chemistry, Organic Chemistry +8

Tandem Rh(I)-Catalyzed [(5+2)+1] Cycloaddition/Aldol Reaction for the Construction of Linear Triquinane Skeleton:  Total Syntheses of (±)-Hirsutene and (±)-1-Desoxyhypnophilin

Lei Jiao, Changxia Yuan, Zhi‐Xiang Yu · Journal of the American Chemical Society · 2008 · 160 citations

Natural Sciences, Chemistry, Medicinal Chemistry +14

Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene

Carley Chandler, Benjamin List · Journal of the American Chemical Society · 2008 · 142 citations

Natural Sciences, Biochemistry, Chemistry +12

Asymmetric approach to Pauson-Khand bicyclization. Enantioselective formal synthesis of hirsutene

Jaume Castro, Antoni Riéra, Christophe Morin et al. · Journal of the American Chemical Society · 1990 · 136 citations

Natural Sciences, Chemistry, Analytical Chemistry +7