The Astrophysical Journal · 2008 · 62 citations · 8 references
Natural SciencesAstronomyChemistryCatalysisPhysical ChemistrySurface ScienceAstrochemical Reaction NetworksCatalysis At SurfacesCatalytic MaterialsGrain-surface ChemistryInterstellar ChemistrySurface CatalysisAmorphous CarbonComplex Organic Molecule FormationFormation Of Complex Organic MoleculesGrain-catalyzed Formation Of Molecular HydrogenGrain-surface Reaction NetworksInterstellar Grain-surface ChemistryPlanetary NebulaeProtoplanetary Nebulae
When hydrogen, nitrogen, and CO are exposed to amorphous iron silicate surfaces at temperatures between 500 and 900 K a carbonaceous coating forms via Fischer-Tropsch-type reactions. Under normal circumstances such a coating would impede or stop further reaction. However, we find that this coating is a better catalyst than the amorphous iron silicates that initiate these reactions. Formation of a self-perpetuating catalytic coating on grain surfaces could explain the rich deposits of macromolecular carbon found in primitive meteorites and would imply that protostellar nebulae should be rich in organic material.
8
Mineralogy and Petrology of Comet 81P/Wild 2 Nucleus Samples
M. E. Zolensky, T. J. Zega, Hajime Yano et al. · Science · 2006 · 645 citations · Full text
The Origin of Comets in the Solar Nebula: A Unified Model
S. J. Weidenschilling · Icarus · 1997 · 431 citations
Natural Sciences, Astronomy, Physics +10