Cellulose 3,5-Dimethylphenylcarbamate Immobilized onto Silica Gel via Copolymerization with a Vinyl Monomer and Its Chiral Recognition Ability as a Chiral Stationary Phase for HPLC

Abstract

Abstract A new cellulose phenylcarbamate derivative having a vinyl group at the 6-position was synthesized and immobilized onto silica gel via radical copolymerization with styrene. The immobilization was efficiently attained using a small amount of styrene. The chiral recognition abilities of the immobilized chiral stationary phase (CSP) were similar to those of the CSP coated on silica gel.