Concepedia

Synthesis of a Hafnocene Disilene Complex

Roland C. Fischer, M. Zirngast, Michaela Flock, Judith Baumgartner, Christoph Marschner

Journal of the American Chemical Society · 2004 · 52 citations · 24 references

DOI

Concepts

Abstract

Reaction of the magnesium transmetalation product of a 1,2-dipotassiodisilane with hafnocene dichloride gives a disilene hafnocene complex. X-ray crystallography of the respective trimethylphosphane adduct provides structural proof for this assignment.

References

24

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