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Design of New Mesogenic Block Molecules: Formation of Columnar Mesophases by Calamitic Bolaamphiphiles with Lateral Lipophilic Substituents
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1999
Year
Supramolecular AssemblyEngineeringMolecular Self-assemblyLateral Lipophilic SubstituentsIncompatible PartsColumnar MesophasesRigid BolaamphiphilesBiophysicsPolymer ChemistrySynthetic MacromoleculeNovel TypeCalamitic BolaamphiphilesMicelleMolecular EngineeringMacromolecular ArchitectureBiomolecular EngineeringSelf-assemblyAmphiphilic SystemPolymer Self-assembly
Rigid bolaamphiphiles with lateral alkyl chains such as 1 form columnar mesophases of a novel type based on microsegregation of the three incompatible parts of the molecules (shown schematically).