Concepedia

Studies on the intramolecular Kulinkovich–de Meijere reaction of disubstituted alkenes bearing carboxylic amide groups

Nouara Ouhamou, Y. Six

Organic & Biomolecular Chemistry · 2003 · 42 citations · 12 references

DOI

Concepts

Abstract

1,2-Disubstituted olefins bearing an acetamide group were found to undergo intramolecular Kulinkovich-de Meijere cyclopropanation in moderate yield but almost complete diastereoselectivity.

References

12

Titanium(IV) Isopropoxide-Catalyzed Formation of 1-Substituted Cyclopropanols in the Reaction of Ethylmagnesium Bromide with Methyl Alkanecarboxylates

Oleg G. Kulinkovich, Sergei V. Sviridov, Dmitry A. Vasilevski · Synthesis · 1991 · 263 citations

, , +5

<b>Nuclear Magnetic Resonance Spectroscopy. Cyclopropane Derivatives</b>

Dinshaw J. Patel, M.E.H. Howden, John D. Roberts · Journal of the American Chemical Society · 1963 · 188 citations

, , +5

A Versatile New Preparation of Cyclopropylamines from Acid Dialkylamides

Vladimir Chaplinski, Armin de Meijere · Angewandte Chemie International Edition in English · 1996 · 168 citations

, , +8

A New Variant of the Kulinkovich Hydroxycyclopropanation. Reductive Coupling of Carboxylic Esters with Terminal Olefins

Jinhwa Lee, Heejin Kim, Jin Kun · Journal of the American Chemical Society · 1996 · 134 citations

, , +5

New and easy route to primary cyclopropylamines from nitriles

Philippe Bertus, Jan Szymoniak · Chemical Communications · 2001 · 91 citations

, , +8