Publication | Closed Access
Total Synthesis of Uniflorine A, Casuarine, Australine, 3-<i>epi</i>-Australine, and 3,7-Di-<i>epi</i>-australine from a Common Precursor
90
Citations
43
References
2009
Year
Bioorganic ChemistryEngineeringOrganic ChemistryChemistryMedicinal ChemistryCommon PrecursorFlexible MethodStereoselective SynthesisUnnatural Epimer 3,7-Di-epi-australineDiversity-oriented SynthesisTotal SynthesisPyrrolizidine AlkaloidsPharmacologyAsymmetric CatalysisNatural Product SynthesisUniflorine AEnantioselective SynthesisBiomolecular EngineeringNatural Sciences
A flexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.
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