Stereoselective synthesis of (E)-alkenylsilanes from aldehydes with a reagent prepared by chromium(II) reduction of Me3SiCHBr2

Simple and selective method for aldehydes (RCHO) .fwdarw. (E)-haloalkenes (RCH:CHX) conversion by means of a haloform-chromous chloride system

Kazuhiko Takai, Koji Nitta, K. UTIMOTO · Journal of the American Chemical Society · 1986 · 747 citations

Chemical Engineering, Engineering, Alkene Metathesis +10

Carbonyl methylenation of easily enolizable ketones

J. HIBINO, Takashi Okazoe, Kazuhiko Takai et al. · Tetrahedron Letters · 1985 · 164 citations

Novel Organocatalysts, Organic Chemistry, Carbonyl Methylenation +3

A highly stereoselective synthesis of vinyl bromides and chlorides via disubstituted vinylsilanes

Rebecca Miller, Glenn J. McGarvey · The Journal of Organic Chemistry · 1978 · 124 citations

Chemical Engineering, Chemical Measurement, Engineering +13

Aldehyde-selective addition of alkynylchromium compounds prepared by reduction of alkynyl halides with chromium(II) reagent

Kazuhiko Takai, Tooru Kuroda, S. NAKATSUKASA et al. · Tetrahedron Letters · 1985 · 115 citations

Chemical Engineering, Derivative (Chemistry), Engineering +8

The Stereochemistry of the Addition of Silicochloroform to Acetylenes. A Comparison of Catalyst Systems

Robert A. Benkeser, Merwyn L. Burrous, Lee E. Nelson et al. · Journal of the American Chemical Society · 1961 · 111 citations

Chemical Engineering, A Comparison, Engineering +13