Chemistry of Materials · 2007 · 191 citations · 85 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryNanomaterialsSurface ScienceCoordination ChemistryCoordination PolymersNanoporous MaterialsPolymer Physical ChemistryPolymer StructurePorous MaterialsIntermolecular Template EffectsMetal-ligand Coordination PolymersMetal-organic FrameworksMolecular Self-assemblyPorous Coordination PolymersPorous NanomaterialsPorous Polymers
In recent years, a new class of porous materials based on a combination of organic components and metal centers has emerged, called porous coordination polymers (PCPs). PCPs have unique characteristics: regular nanosized spaces, flexibility, and a designed pore surface. The interaction between PCP nanospaces and guest molecules controls the nanoscale molecular assembly. In this short review, correlations between PCPs and guest molecules will be introduced under the rubric of “template”.
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