Chemical Communications · 2000 · 40 citations · 2 references
Natural SciencesChemistryCatalysisOrganic ChemistryOrganometallic ChemistryAcid-base ChemistryChemical BondingCoordination ChemistryHeterocycle SynthesisHeterocyclic ChemistryOrganic SynthesisBorylation ReactionsElectrophilic Aromatic SubstitutionElectrophilic CatalysisElectrophilic Substitution In HeterocyclesLewis Acid CatalysisLewis Acid-base TheoryLewis AcidityReactive Intermediates In Organometallics
It has been found that 1H-2,1-benzazaboroles can be prepared by the interaction of substituted benzylaminochloroboranes with Al2Cl6 in CH2Cl2 at 0 °C, the 13C NMR spectroscopy data obtained being in favour of an electrophilic substitution mechanism involving formation of cationic complexes as reactive intermediates.
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