Synthesis and Structure Analysis of (K[DB18 C6])₄(C₆₀)₅⋅12 THF Containing C₆₀ in Three Different Bonding States

Abstract

A new fulleride, (K[DB18C6])(4)(C(60))(5)·12THF, was prepared in solution using the "break-and-seal" approach by reacting potassium, fullerene, and dibenzo[18]crown-6 in tetrahydrofuran. Single crystals were grown from solution by the modified "temperature difference method". X-ray analysis was performed revealing a reversible phase transition occurring on cooling. Three different crystal structures of the title compound at different temperatures of data acquisition are addressed in detail: the "high-temperature phase" at 225 K (C2, Z=2, a=49.055(1), b=15.075(3), c=18.312(4) Å, β=97.89(3)°), the "transitional phase" at 175 K (C2 m, Z=2, a=48.436(5), b=15.128(1), c=18.280(2) Å, β=97.90(1)°), and the "low-temperature phase" at 125 K (Cc, Z=4, a=56.239(1), b=15.112(3), c=36.425(7) Å, β=121.99(1)°). On cooling, partial radical recombination of C(60)(·-) into the (C(60))(2)(2-) dimeric dianion occurs; this is first time that the fully ordered dimer has been observed. Further cooling leads to formation of a superstructure with doubled cell volume in a different space group. Below 125 K, C(60) exists in the structure in three different bonding states: in the form of C(60)(·-) radical ions, (C(60))(2)(2-) dianions, and neutral C(60), this being without precedent in the fullerene chemistry, as well. Experimental observations of one conformation exclusively of the fullerene dimer in the crystal structure are further explained on the basis of DFT calculations considering charge distribution patterns. Temperature-dependent measurements of magnetic susceptibility at different magnetic fields confirm the phase transition occurring at about 220 K as observed crystallographically, and enable for unambiguous charge assignment to the different C(60) species in the title fulleride.