Gamma-induced modifications of polycarbonate polymer

Abstract

Gamma-induced modifications in polycarbonate polymer have been studied in the dose range of 101–106 Gy. Thin films of polycarbonate have been irradiated with different gamma doses from a Co60 source. To monitor the modifications caused by gamma radiation, FT-IR, differential scanning calorimetry and X-ray diffraction studies have been performed. The studies have indicated that at the dose of 106 Gy, phenolic group forms through scissioning of ester linkage. Though the effect of radiation is most significant at the highest dose, the process of modifications starts at 103 Gy. Scissioning of the polymeric chain initiates a different morphological zone within the polymer matrix, and the polymer becomes more crystalline with increasing dose. Owing to chain scissioning, the mobility of the polymer increases, which in turn reduces the glass transition temperature of the polymer.