Publication | Closed Access
A Novel Synthesis of Hexakis(trifluoromethyl)cyclotriphosphazene. Single-Crystal X-ray Structures of N<sub>3</sub>P<sub>3</sub>(CF<sub>3</sub>)<sub>6</sub> and N<sub>3</sub>P<sub>3</sub>F<sub>6</sub>
35
Citations
9
References
1999
Year
X-ray CrystallographyInorganic ChemistryMaterials ScienceCrystal StructureEngineeringCatalytic AmountNatural SciencesFluorous SynthesisOrganic ChemistryNovel SynthesisChemistrySingle-crystal X-ray StructuresCrystallographyCrystal Structure DesignBiomolecular EngineeringCesium Fluoride
Reaction of hexafluorocyclotriphosphazene (N3P3F6) with trimethyl(trifluoromethyl)silane in the presence of a catalytic amount of cesium fluoride in THF produced hexakis(trifluoromethyl)cyclotriphosphazene [N3P3(CF3)6] in 90% isolated yield. N3P3(CF3)6 is fully characterized by melting point, IR, NMR (19F, 13C, 31p), MS, and elemental analysis data. Single-crystal X-ray structures of N3P3(CF3)6 and N3P3F6 are reported.
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