Stable, trinuclear Zn(ii)- and Cd(ii)-metallocycles: TWIM-MS, photophysical properties, and nanofiber formation

Anthony Schultz, Yan Cao, Mingjun Huang, Stephen Z. D. Cheng, Xiaopeng Li, Charles N. Moorefield, Chrys Wesdemiotis, George R. Newkome

Dalton Transactions · 2012 · 40 citations · 18 references

Concepts

Abstract

A series of trimeric, Zn(II)- and Cd(II)-metallocycles is reported. Structural characterization of the highly stable triangles was supported by traveling-wave ion mobility-mass spectrometry (TWIM-MS) and gradient tandem mass spectrometry (gMS(2)). Their unique photophysical properties and self-assembly to form nanofibers are also described.

References

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