Piezoelectric Properties and Phase Relations of Pb(Mg _1/3 Nb _2/3 )O ₃ ‐PbTiO ₃ −PbZrO ₃ Ceramics with Barium or Strontium Substitutions

Abstract

When a small amount of Ba or Sr is substituted for Pb in Pb(Mg 1/3 Nb 2/3 )O 3 ‐PbTiO 3 ‐Pb2rO 3 , the morphotropic boundary and the compositions which show the highest planar coupling coefficient and dielectric constant shift slightly toward the decreasing PbTiO 3 content. The tetragonality of Pb(Mg 1/3 Nb 2/3 )O 3 ‐PbTiO 3 and Pb(Mg 1/2 Nb 2/3 )‐O 3 ‐PbTiO 3 ‐PbZrO 3 ceramics decreased with increasing Ba or Sr content. The lattice parameter (α axis) in the rhombohedral or pseudocubic phase increased with the increase of Ba but decreased with the increase of Sr substitution. Although the Curie temperature was lowered with the increase of Ba or Sr, the dielectric constants of the ceramics were increased. The dielectric and piezoelectric properties of the ternary compositions near the morphotropic boundary were improved through selection of sub‐stituent and base composition. A planar coupling coefficient of 0.66 and a low Young's modulus were obtained with substitution of 5 mole % Ba. A dielectric constant greater than 3500 and a planar coupling of 0.63 can be obtained by substituting 5 mole % Sr.