Publication | Closed Access
Hydrothermal Synthesis of Microporous Transition Metal Squarates: Preparation and Structure of [CO<sub>3</sub>(μ<sub>3</sub>‐OH)<sub>2</sub>(C<sub>4</sub>O<sub>4</sub>)<sub>2</sub>]·3H<sub>2</sub>O
104
Citations
8
References
1997
Year
EngineeringCobalt Hydroxide BackboneChemistryInorganic CompoundStructure ElucidationHydrothermal SynthesisMaterials ScienceInorganic ChemistryBiochemistryCatalysisCrystallographyInorganic SynthesisCatalytic SynthesisExperimental SynthesisMicroporous Transition MetalNatural SciencesCoordination ComplexSquarate LigandsCatalyst PreparationFunctional MaterialsMetal HydroxideHydrothermal Processing
A cobalt hydroxide backbone with a structure reminiscent of that found in cobalt(II) hydroxide forms the basis of the framework of the title compound. The squarate ligands of this coordination solid link the metal hydroxide strips together and form the walls of channels with a diameter of approximately 7 Å.
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