Concepedia

Hydrothermal Synthesis of Microporous Transition Metal Squarates: Preparation and Structure of [CO<sub>3</sub>(μ<sub>3</sub>‐OH)<sub>2</sub>(C<sub>4</sub>O<sub>4</sub>)<sub>2</sub>]·3H<sub>2</sub>O

Siegfried O. H. Gutschke, Michel Molinier, Annie K. Powell, Paul T. Wood

Angewandte Chemie International Edition in English · 1997 · 105 citations · 8 references

DOI

Concepts

Abstract

A cobalt hydroxide backbone with a structure reminiscent of that found in cobalt(II) hydroxide forms the basis of the framework of the title compound. The squarate ligands of this coordination solid link the metal hydroxide strips together and form the walls of channels with a diameter of approximately 7 Å.

References

8

Structural Inorganic Chemistry

Colin Eaborn · Journal of Organometallic Chemistry · 1985 · 2.8K citations

Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels

Omar M. Yaghi, Hailian Li · Journal of the American Chemical Society · 1995 · 2K citations

, , +9

Hydrothermal chemistry of zeolites

Edith M. Flanigen · Zeolites · 1983 · 802 citations

, , +9

Giant Voids in the Hydrothermally Synthesized Microporous Square Pyramidal−Tetrahedral Framework Vanadium Phosphates [HN(CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>NH]K<sub>1.35</sub>[V<sub>5</sub>O<sub>9</sub>(PO<sub>4</sub>)<sub>2</sub>]·<i>x</i>H<sub>2</sub>O and Cs<sub>3</sub>[V<sub>5</sub>O<sub>9</sub>(PO<sub>4</sub>)<sub>2</sub>]·<i>x</i>H<sub>2</sub>O

Mohammed Isaque Khan, Linda M. Meyer, Robert C. Haushalter et al. · Chemistry of Materials · 1996 · 213 citations

, , +11

The Trapping of Iron Hydroxide Units by the Ligand “heidi”: Two New Hydroxo(oxo)iron Clusters Containing 19 and 17 Iron Atoms

S.L. Heath, Annie K. Powell · Angewandte Chemie International Edition in English · 1992 · 141 citations

, , +6