Sum Rules for Variational Wavefunctions

A. Dalgarno, Saul T. Epstein

The Journal of Chemical Physics · 1969 · 84 citations · 5 references

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Abstract

It is demonstrated that the finite set of wavefunctions obtained by applying the variational principle to a linear combination of basis functions provides bonds to a number of sum rules and that by appropriate choice of the basis functions certain of the sum rules can be satisfied exactly.

References

5