Russian Chemical Reviews · 2004 · 51 citations · 3 references
Natural SciencesChemistryCatalysisEnzyme MechanismReaction EngineeringCatalytic MechanismsCatalytic Reaction EngineeringCatalytic Reaction KineticsRadical ReactionsSpin DynamicsSpin-orbit CouplingAngular Momentum ConservationChemical Reaction MechanismsHeterogeneous Chemical ReactionsSpin PhysicsSpin States
A new phenomenon, spin catalysis, i.e., stimulation of chemical reactions by removing the prohibitions imposed for reasons of electron angular momentum (spin) of reactants is considered. The physical and chemical mechanisms of this phenomenon are discussed. The nature of spin catalysts, the quantitative measure of catalytic effects and the types of chemical reactions susceptible to spin catalysis are considered. The bibliography includes 37 references.
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Spin catalysis of the radical recombination reaction
A. L. Buchachenko, L. V. Ruban, Eugene N. Step et al. · Chemical Physics Letters · 1995 · 37 citations · Full text