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Catalytic Hydrogenation of α‐Iminophosphonates as a Method for the Synthesis of Racemic and Optically Active α‐Aminophosphonates
59
Citations
55
References
2008
Year
EngineeringOrganic ChemistryChemistryRhodium‐catalyzed Enantioselective HydrogenationChemical EngineeringMolecular HydrogenOrganometallic CatalysisStereoselective SynthesisDiversity-oriented SynthesisCatalysisHydrogenSynthesis MethodAsymmetric CatalysisEnantioselective SynthesisBiomolecular EngineeringOptically Active α‐AminophosphonatesNatural SciencesCatalytic HydrogenationSynthetic Chemistry
Abstract It was shown that the catalytic hydrogenation of α‐iminophosphonates by molecular hydrogen can serve as a convenient method for the synthesis of racemic and optically active α‐aminophosphonates. Up to 94% ee was achieved in the rhodium‐catalyzed enantioselective hydrogenation using chiral ligand ( R )‐BINAP.
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