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Palladium‐Catalyzed Synthesis of Propellanes with Hexaarylethane Structure
36
Citations
18
References
1997
Year
Abstract Areno‐anellatedInorganic ChemistryCross-coupling ReactionEngineeringCatalytic SynthesisPentalene System 8Palladium‐catalyzed DominoCatalysisOrganometallic CatalysisChemistryHexaarylethane StructureSynthetic ChemistryBiomolecular Engineering
Abstract Areno‐anellated [3.3. n ]propellanes with n = 2, 3, and 4 are easily accesible by palladium‐catalyzed domino coupling processes of the pentalene system 8 with various aryl iodides. The X‐ray structure investigations reveled a noteworthy elongation of the central CC single bond of these propellanes to ca. 162 pm.
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