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Mixed valence manganese-(<scp>II</scp>,<scp>III</scp>) and -(<scp>III</scp>,<scp>IV</scp>) dinuclear complexes: preparation, structure, magnetochemistry, and e.s.r. spectra of Mn<sub>2</sub>(biphen)<sub>2</sub>(biphenH)(bpy)<sub>2</sub>and Mn<sub>2</sub>O<sub>2</sub>Cl<sub>2</sub>(OAc)(bpy)<sub>2</sub>(biphenH<sub>2</sub>= 2,2′-biphenol, bpy = 2,2′-bipyridine)
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1988
Year
Materials ScienceInorganic ChemistryMagnetic PropertiesMagnetismMixed Valence Manganese-EngineeringCoordination ComplexMagnetic ResonanceMolecular ComplexChemistryRare S= 9/2Magnetization StudiesGround StateInorganic SynthesisInorganic Compound
The preparation and properties of two new mixed valence Mn complexes, Mn2(biphen)2(biphenH)(bpy)2(3) and Mn2O2Cl2(OAc)(bpy)2(2)(bpy = 2,2′-bipyridine, biphenH2= 2,2′-biphenol) are reported; complex (3) has a rare S= 9/2 ground state confirmed by magnetization studies.