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Photoinduced Wolff Rearrangement of α-Diazo-β-Ketophosphonates : A Novel Entry into Substituted Phosphonoacetates
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Citations
2
References
1984
Year
EngineeringSynthetic PhotochemistryOrganic ChemistryChemistryAbstract Direct IrradiationPhotoredox ProcessStereoselective SynthesisMany Ses-quiterpenesFunctionalized Isopropyl GroupBiochemistryPhotochemistryMechanistic PhotochemistryDiversity-oriented SynthesisSubstituted PhosphonoacetatesNovel EntryPhotoinduced Wolff RearrangementEnantioselective SynthesisBiomolecular EngineeringNatural SciencesSynthetic Chemistry
Abstract Direct irradiation (254 nm) of α-diazo-β-ketophosphona-tes in the presence of an alcohol, leads to substituted phosphonoacetates. This allows a novel construction of the functionalized isopropyl group present in many ses-quiterpenes.
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