Publication | Closed Access
Phosphinimides as a Steric Equivalent to Cyclopentadienyl: An Approach to Ethylene Polymerization Catalyst Design
181
Citations
27
References
1999
Year
Steric EquivalentInorganic ChemistryChemical EngineeringEthylene PolymerizationEngineeringAlkene MetathesisCoordination ComplexPolymer ScienceActive CatalystsOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAnalogous Dimethyl DerivativesPolymer ReactionInorganic SynthesisPolymer ChemistryPolymer Synthesis
Complexes of the form (Cp†)TiCl2(NPR3) and the analogous dimethyl derivatives (Cp†)TiMe2(NPR3) have been prepared. These species in the presence of MAO, B(C6F5)3, or [Ph3C][B(C6F5)4] are active catalysts for ethylene polymerization.
| Year | Citations | |
|---|---|---|
Page 1
Page 1