Water Immobilization at Surfactant Interfaces in Reverse Micelles

Abstract

The mobility of water in water/Aerosol OT (AOT)/isooctane reverse micelles has been investigated via polar solvation dynamics measurements using ultrafast, time-resolved fluorescence-upconversion spectroscopy. For the smallest reverse micelles studied, w 0 = 1.1, no solvation dynamics are observed on the time scale of the instrument, suggesting that the water is essentially frozen. As w 0 increases, the mobility of water increases, and the time-correlation functions exhibit multiexponential decays. A subpicosecond component is observed on a time scale similar to that of diffusive bulk-water motion. 1 The other components decay on time scales of a few picoseconds to hundreds of picoseconds. The amplitude of the solvent response increases as w 0 increases, which is attributed to increased mobility of the water inside the reverse micelles. Because the micellar interior is highly ionic, the solvation dynamics of coumarin 343 in a 1 M Na + (Na 2 SO 4 ) solution were also investigated to compare the dynamics of water in the reverse micelles with the dynamics of bulk water in an ionic solution.