Carbon–carbon bond formation by alkyne–µ,η<sup>2</sup>-acetylide and alkyne–CO coupling in the reaction of (OC)<sub>5</sub>MCCPH (M = MN, Re) with HOs<sub>3</sub>(CO)<sub>10</sub>(µ,η<sup>2</sup>-CCPh). X-Ray structure of HOs<sub>3</sub>Re(CO)<sub>14</sub>(C<sub>2</sub>Ph)<sub>2</sub> - Concepedia

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Carbon–carbon bond formation by alkyne–µ,η<sup>2</sup>-acetylide and alkyne–CO coupling in the reaction of (OC)<sub>5</sub>MCCPH (M = MN, Re) with HOs<sub>3</sub>(CO)<sub>10</sub>(µ,η<sup>2</sup>-CCPh). X-Ray structure of HOs<sub>3</sub>Re(CO)<sub>14</sub>(C<sub>2</sub>Ph)<sub>2</sub>

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References

1984

Year

A.A. Koridze, O.A. Kizas, N E Kolobova, V. N. Vinogradova, Nikolai A. Ustynyuk, P. V. Petrovskii, A.I. Yanovsky, Yu. T. Struchkov

Journal of the Chemical Society Chemical Communications

Abstract

Addition of (OC)5MCCPh (M = Mn,Re) to HOs3(CO)10(µ,η2-CCPh) leads to the formation of carbon–carbon bonds under mild conditions to yield metal cluster compounds HOs3M(CO)14(C2Ph)2; the cluster HOs3Re(CO)14(C2Ph) has been characterized by an X-ray structure analysis.