Organische Elektronenleiter und Vorstufen. V. Synthese von Poly(organylthio‐acetylenen)

Abstract

Organic Electron Conductors and Precursors. V. Synthesis of Poly (organylthio‐acetylenes) Poly(bis‐organylthio‐acetylenes) 2 and poly(mono‐organylthio‐acetylenes) 3 have been synthesized by complex catalyzed polymerization of the corresponding acetylenes ( 4 resp. 5 ). Yields and properties of the polymers 2 , 3 depend on reaction conditions, the catalyst and the nature of the acetylenes. Relations between these influence factors are discussed.