Corrosion inhibition of steel in molar HCl by triphenyltin2–thiophene carboxylate

Abstract

The effect of triphenyltin2–thiophene carboxylate (TTC) on the corrosion of steel in hydrochloric acid medium was studied using gravimetric, electrochemical polarisation and electrochemical impedance spectroscopy (EIS) measurements. The percentage inhibition efficiency was found to increase with increasing concentration of inhibitor to reach 97% at 10−3 M. Polarisation study shows that TTC is an efficient inhibitor and acts as a mixed-type inhibitor. EIS results indicate the increase of resistance transfer (RT) and the decrease of double layer capacitance (Cdl) with TTC concentration. Triphenyltin2–thiophene carboxylate molecules lead to the formation of a protective layer on the surface of steel. The inhibitor is adsorbed on the steel surface according to Langmuir isotherm.