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Copper‐Catalyzed Three‐Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic Acid
176
Citations
97
References
2013
Year
Room TemperatureChemical EngineeringDerivative (Chemistry)EngineeringSodium TrifluoromethanesulfinateAlkene MetathesisFluorous SynthesisHydroxamic AcidOrganic ChemistryOrganometallic CatalysisCatalysisChemistryThree‐component OxytrifluoromethylationPharmacologyChemical DerivativeOnline DeliveryRadical Paths
Radical paths: The title reaction of olefins with NaSO2CF3 and N-hydroxy-N-phenylacetamide at room temperature is described for the first time (see scheme). This reaction provides a practical and convenient route to a series of trifluoromethylated alcohols bearing a wide range of functional groups. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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