Electrochemical and Solid-State Letters · 2007 · 50 citations · 19 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryInorganic ChemistryElectrode MaterialsElectrode-electrolyte InterfacesElectrolyte MaterialsMetal Oxide NanomaterialsMetal OxidesSolid-state ElectrolytesAnodizationElectrochemical PotentialsElectrochemical TransportNickel OxidesOxide ElectrolytesOxide Growth KineticsOxide StructureX-ray Diffraction Analysis
The formation of niobium oxide microcones on niobium substrates was investigated in electrolytes. The microstructure of the layers depends strongly on the concentration, the formation potential, and the anodization time. Microcones can be formed under a range of experimental conditions. Electrochemical determination and scanning electron microscopy indicate the microcones were formed due to the fast expansion of the oxide volume and the electric break under electric field. X-ray diffraction results verify the formation of . A possible growth mechanism has also been presented on the basis of experiments.
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Self-organized porous WO3 formed in NaF electrolytes
Hiroaki Tsuchiya, Jan M. Macák, I. Sieber et al. · Electrochemistry Communications · 2005 · 251 citations
Natural Sciences, Materials Engineering, Materials Science +14
On the oxidation and on the superconductivity of niobium
J. Halbritter · Applied Physics A · 1987 · 240 citations