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Lewis Base Catalyzed Trifluoromethylation of Carbonyl Compounds with Trialkyl(trifluoromethyl)silanes
42
Citations
10
References
1997
Year
Carbonyl CompoundsChemical EngineeringAsymmetric TrifluoromethylationEngineeringOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisChiral Lewis BasesEnantioselective SynthesisMany Lewis Bases
Many Lewis bases effectively catalyze the trifluoromethylation of carbonyl compounds with trimethyl(trifluoromethyl)silane. By using chiral Lewis bases as catalysts, asymmetric trifluoromethylation was achieved. The higher enantiomer excesses were ob
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