Concepedia

Taming functionality: easy-to-handle chiral phosphiranes

Arne Ficks, Ivan Martinez‐Botella, Beverly Stewart, Ross W. Harrington, W. Clegg, Lee J. Higham

Chemical Communications · 2011 · 39 citations · 20 references

DOIFull text

Open access

Concepts

Abstract

Enantiopure chiral phosphiranes possessing a binaphthyl backbone demonstrate remarkable thermal stability, are highly resistant to air-oxidation and are effective ligands in catalytic asymmetric hydrosilylations.

References

20

Phosphiran

Ross I. Wagner, LeVern D. Freeman, Harold Goldwhite et al. · Journal of the American Chemical Society · 1967 · 88 citations

, , +9

Palladium-catalysed asymmetric hydrosilylation of styrenes with a new chiral monodentate phosphine ligand

Kenji Kitayama, Yasuhiro Uozumi, Tamio Hayashi · Journal of the Chemical Society Chemical Communications · 1995 · 86 citations

, , +11

Phosphiranes as Ligands for Platinum Catalysed Hydrosilylations

Jürgen Liedtke, Sandra Loss, Christoph Widauer et al. · Tetrahedron · 2000 · 78 citations

, , +1

Synthesis of optically active phosphiranes and their use as ligands in rhodium(I) complexes

Angéla Marinetti, François Mathey, Louis Ricard · Organometallics · 1993 · 63 citations

, , +15

Synthetic, Structural, and Solution Thermochemical Studies in the Dimethylbis(phosphine)platinum(II) System. Dichotomy between Structural and Thermodynamic Trends

Christopher M. Haar, Steven P. Nolan, William Marshall et al. · Organometallics · 1999 · 58 citations

, , +13