Fabrication of Hollow Melamine−Formaldehyde Microcapsules from Microbubble Templates

Abstract

A fabrication method for hollow melamine-formaldehyde microcapsules from microbubble templates is presented. This method is based on the direct encapsulation of microbubbles, and thus does not require a liquid- or solid-core decomposition process. This study determined the conditions for controlling the surface morphology, shell thickness, and diameter distribution of hollow microcapsules. Results showed that the surface morphology of these hollow microcapsules depended on the reaction time, glycine concentration (pH of aqueous continuous phase) and pre-polymer concentration. The capsule shell thickness could be controlled by adjusting the concentration of aniline that had adsorbed on the microbubble surface and reacted with pre-polymer. The capsule diameter depended on the dissolution rate of gases, and the diameter of the hollow microcapsules fabricated from air microbubble templates ranged from 5 to 200 microm.