Concepedia

Some single electron-transfer reactions of arylimines

David W. Brown, Monika Lindquist, Mary F. Mahon, Bengt Malm, Göran N. Nilsson, Aleyamma Ninan, M. Sainsbury, Christer Westerlund

Journal of the Chemical Society Perkin Transactions 1 · 1997 · 10 citations · 9 references

DOI

Concepts

Abstract

When treated with suitable alkyllithiums, arylimines may undergo single electron-transfer and conjugative substitution in the aryl ring, as well as nucleophilic addition to the imine bond. Multiple substitutions by tert-butyl radicals are noted, giving rise to rearranged and oxidized products, including cycloadducts.

References

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Phase annealing in SHELX-90: direct methods for larger structures

George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 1990 · 16.3K citations

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<i>ORTEX</i>2.1 – a 1677-atom version of<i>ORTEP</i>with automatic cell outline and cell packing for use on a PC

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Metal—halogen interchange between -butyllithium and 1-iodo-5-hexenes provides no evidence for single-electron transfer

William F. Bailey, Jeffrey J. Patricia, Timo Nurmi et al. · Tetrahedron Letters · 1986 · 60 citations

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Reactions of alkali benzophenone ketyls with alkyl iodides

John F. Garst, Calvin D. Smith · Journal of the American Chemical Society · 1976 · 52 citations

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THE FORCED REACTION OF PHENYL ISOCYANATE, PHENYL ISOTHIOCYANATE AND BENZOPHENONE-ANIL WITH PHENYLMAGNESIUM BROMIDE. AN UNUSUAL TYPE OF 1,4-ADDITION TO A CONJUGATED SYSTEM THAT IS PART ALIPHATIC AND PART AROMATIC

Henry Gilman, James E. Kirby, Corliss R. Kinney · Journal of the American Chemical Society · 1929 · 41 citations

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