Physical Review · 1925 · 637 citations · 5 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryMaterials CharacterizationMetallic MaterialsAlloysCrystal ChemistryCrystallographyMetal MaterialsMetalsX-ray DiffractionLattice ConstantsMetalloid Materials CharacterizationPrecision
The study employed high‑purity samples (99.55–99.9995 %) and, for bismuth, a single artificial crystal to measure lattice constants. Lattice constants for twelve common metals were measured to within 0.1 % (0.03 % for W) by comparison with NaCl, revealing higher X‑ray derived densities than literature values for most metals and exceptionally sharp diffraction lines for pure tungsten.
The lattice constant $a$ has been determined within 0.1 percent (.03 percent for W) for aluminum, iron, nickel, copper, molybdenum, palladium, silver, tungsten, platinum, gold, lead and bismuth, by direct comparison with NaCl, $a(\mathrm{NaCl})=2.814$A. As pure samples as could be obtained were used, from 99.55 percent for Ni to 99.9995 percent for tungsten, and in many cases commercially pure samples were also measured for comparison. The results for the purest samples are summarized in Table XIII. The density from the x-ray data is in each case (except Al and Ag) greater than the density of the bulk metal as given in the literature, the difference being rather large for Mo (10.21 vs 9.1), for Pd (12.25 vs 11.9) and W (19.32 vs 18.77). For pure W remarkably sharp lines were obtained. For Bi a piece of a single artificial crystal was used.
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The Absolute Sizes of Certain Monovalent and Bivalent Ions
Wheeler P. Davey · Physical Review · 1922 · 45 citations
A New X-Ray Diffraction Apparatus
Wheeler P. Davey · Journal of the Optical Society of America · 1921 · 10 citations · Full text