A Rare Uninodal 9-Connected Metal−Organic Framework with Permanent Porosity

Abstract

A rare uninodal 9-connected metal−organic framework (Zn3(TAA)3(H2O)3·(1,4-dioxane) (MOF 1) (TAA = 1-H-tetrazole-5-acetate) was synthesized, structurally characterized, and topologically rationalized as a vnd net, exhibiting permanent porosity, and solvent-dependent luminescence properties.