Spin Crossover Bistability in Three Mutually Perpendicular Interpenetrated (4,4) Nets

Abstract

[EN] The synthesis, crystal structure, magnetic properties, and Mossbauer spectra of [Fe(bpb)(2)(NCS)(2)](.)0.5CH(3)OH (1) (bpb = 1,4-bis(4-pyridyl)-butadiyne) are reported. 1 is a singular example of the interpenetration of three mutually perpendicular nets with spin crossover properties.