Concepedia

The preparation and crystal structures of two diphenylantimony triacetate hydrolysis products: [Ph<sub>2</sub>Sb(OAc)<sub>2</sub>]<sub>2</sub>O and [(Ph<sub>8</sub>Sb<sub>4</sub>O<sub>6</sub>)·(HOAc)<sub>3</sub>]·CH<sub>2</sub>Cl<sub>2</sub>

D. Bryan Sowerby, Michael J. Begley, Peter L. Millington

Journal of the Chemical Society Chemical Communications · 1984 · 20 citations · 0 references

DOI

Concepts

Abstract

Diphenylantimony triacetate undergoes ready hydrolysis to give the oxygen-bridged compound [Ph2Sb(OAc)2]2O containing seven-coordinate antimonyl(V) atoms, and [(Ph8Sb4O6)(HOAc)3] containing a non-adamantane Sb4O6 cage.