A Novel Nonlinear Optical Complex Crystal with an Organic Ligand Coordinated through an O Atom: Tetrathiocyanatocadmiummercury-Dimethyl Sulfoxide

Shiyi Guo, Dong Xu, Ping Yang, W.-T. Yu, Meizhe Lv, Dongsheng Yuan, Z.H. Yang, Guanghui Zhang, Shengnan Sun, Xinqiang Wang,

Crystal Research and Technology · 2001 · 15 citations · 0 references

Concepts

Abstract

A novel nonlinear optical complex crystal with an organic ligand coordinated through an O atom: tetrathiocyanatocadmiummercury-dimethyl sulfoxide, [CdHg(SCN)4(H6C2OS)2], (CMTD) is reported for the first time. Single crystals have been grown by temperature-lowering method, the crystals tructure has been determined, and some physical properties are given. The relations between the crystal structure and nonlinear optical properties are also discussed.