Concepedia

Aldehydes and Ketones Epoxidation with Trimethylsulfonium Bromide in a Slightly Hydrated Solid-Liquid Medium

H. Bouda, M.E. Borredon, Michel Delmas, A. Gaset

Synthetic Communications · 1987 · 21 citations · 15 references

DOI

Concepts

Abstract

Abstract Trimethylsulfonium bromide used in low hydrated solid-liquid phase transfer conditions is a very efficient agent for aldehyde and ketone epoxidation.

References

15

Methylsulfinyl Carbanion (CH<sub>3</sub>-SO-CH<sub>2</sub><sup>-</sup>). Formation and Applications to Organic Synthesis

E. J. Corey, Michael Chaykovsky · Journal of the American Chemical Society · 1965 · 523 citations

, , +4

Chemistry of sulfoxides and related compounds. XLVIII. Mechanism of nucleophilic alkylidene transfer by sulfonium and oxosulfonium ylides

Carl R. Johnson, Calvin W. Schroeck, James R. Shanklin · Journal of the American Chemical Society · 1973 · 139 citations

, , +4

Synthesis of oxiranes from aqueous solutions of simple alkyl, allyl, and benzylsulfonium salts

Melvin J. Hatch · The Journal of Organic Chemistry · 1969 · 67 citations

, , +5

Chemistry of sulfoxides and related compounds. XXXIV. Mechanism of sulfonium ylide reactions. Synthesis of cyclopropanes and oxiranes of high optical purity

Carl R. Johnson, Calvin W. Schroeck · Journal of the American Chemical Society · 1971 · 66 citations

, , +4

Phase‐transfer‐catalyzed Production of Sulfur Ylides in an Aqueous System

Andreas Merz, Gottfried Märkl · Angewandte Chemie International Edition in English · 1973 · 60 citations

, , +12