Concepedia

Role of pentahedrally coordinated titanium in titanium silicalite-1 in propene epoxidation

Yi Zuo, Min Liu, Ting Zhang, Luwei Hong, Xinwen Guo, Chunshan Song, Yongsheng Chen, Pengyu Zhu, Cherno Jaye, Daniel A. Fischer

RSC Advances · 2015 · 82 citations · 40 references

DOI

Concepts

Abstract

A new pentahedrally coordinated Ti was discovered in TS-1 and showed a higher catalytic activity than the tetrahedrally coordinated one.

References

40

Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite

M.G. Clerici, Patrizia Ingallina · Journal of Catalysis · 1993 · 729 citations

, , +5

Oxyfunctionalization of alkanes with hydrogen peroxide on titanium silicalite

Diane Huybrechts, L. De Bruycker, Peter A. Jacobs · Nature · 1990 · 435 citations

, , +3

XAFS Study of Ti-Silicalite: Structure of Framework Ti(IV) in the Presence and Absence of Reactive Molecules (H2O, NH3) and Comparison with Ultraviolet-Visible and IR Results

Silvia Bordiga, S. Coluccia, Carlo Lamberti et al. · The Journal of Physical Chemistry · 1994 · 389 citations

, , +17

Synthesis, Crystallization Mechanism, and Catalytic Properties of Titanium-Rich TS-1 Free of Extraframework Titanium Species

Weibin Fan, Ren‐Guan Duan, Toshiyuki Yokoi et al. · Journal of the American Chemical Society · 2008 · 388 citations

, , +14

The state of Ti in titanoaluminosilicates isomorphous with zeolite .beta.

Teresa Blasco, Miguel Á. Camblor, Avelino Corma et al. · Journal of the American Chemical Society · 1993 · 379 citations

, , +19